Under the combined assault of coastal salt spray and industrial acid rain, traditional galvanized steel wires typically rust and fail within 3-5 years, while the service life of zinc-aluminum alloy coated (Zn-5%Al) steel wires can be extended to 8-15 years. Its revolutionary advantages stem from three core technical principles:
"Dual-Protection" Mechanism
Traditional galvanizing relies solely on the sacrificial anode protection of zinc; once the zinc layer is depleted, the iron substrate corrodes rapidly.
In zinc-aluminum alloy coatings, 5% aluminum forms a dense Al-Zn-Si ternary eutectic phase (microscopically exhibiting a lamellar structure) with zinc, simultaneously achieving:
Physical barrier: The Al₂O₃ film formed by aluminum oxidation blocks the penetration of corrosive media.
Electrochemical protection: Zinc continuously acts as a sacrificial anode, delaying corrosion of the substrate.
Self-Healing Capability
When the coating surface is scratched:
Scratches on traditional galvanized coatings undergo explosive rusting (due to exposed cathodes).
In zinc-aluminum coatings, zinc-rich phases rapidly migrate to the damaged area, oxidize to form a new protective film, and block the corrosion pathway.
Anti-Localized Corrosion Properties
In coastal environments with chloride ion concentrations exceeding 500ppm:
Galvanized layers are prone to deep pitting corrosion (with a corrosion rate of up to 0.5mm/year).
Due to aluminum stabilizing corrosion products, zinc-aluminum coatings form a dense protective layer of basic zinc chloride (Zn₅(OH)₈Cl₂), suppressing the pitting rate to 0.05mm/year (measured per ASTM G46).
Verification of Engineering Value:
A seaport guardrail in Fujian: Traditional galvanized steel wires suffered extensive rusting and breakage after 4 years of use; after replacement with zinc-aluminum alloy coated wires, only minor surface spots appeared after 8 years.
40% reduction in life-cycle costs: Over a 20-year service cycle, the comprehensive maintenance cost of zinc-aluminum alloy coatings is lower than that of galvanizing.
Zinc-aluminum alloy coating represents a paradigm shift in corrosion control—infusing engineering with "longevity genes" through materials science.
Allen